Search This Blog

Tuesday, May 6, 2014

Riding on a sunbeam

The solar reactor and researcher team at ETH Zürich
THERE is a ray of hope for us car addicts who must pay whatever the pushers demand for our next fix of diesel or petrol, for scientists at the EU-funded Solar Jet this week showed how concentrated sunlight can be used to convert carbon dioxide and water into jet fuel.
Their proof-of-concept is a major step towards the new scientific holy grail: finding ways to convert, store and transport the energy in a beam of sunlight using thermodynamic theory.
A ray of sunshine does not have a lot of energy, but if you focus a few rays of sunlight with a parabolic dish they will quickly melt a hole through most metals. Enough heat from concentrated sunlight also splits water into its hydrogen and oxygen components.
The process is now long proven — the challenge is to leave the laboratory standing when the split happens.
The jet fuel and by-products produced by Solar Jet.

The red-ox cycle and some WWII know-how

One way is the red-ox cycle, which abbreviates reduction oxidation and first uses the sun’s heat to heat up a metal oxide until all the oxygen has parted ways with the metal.
The red-ox cycle then uses the naked metal to lure the oxygen molecules in water to make a bit of rust, leaving the hydrogen free to become fuel for someone’s car or aeroplane.
Solar Jet added carbon dioxide to the red-ox cycle to let the fake sun turn water into hydrogen and carbon monoxide, also known as syngas (for synthesis gas).
Syngas is organic chemistry’s Lego, being the building block of several commodities, including methanol.
Dr Andreas Sizmann, the project co-ordinator at Bauhaus Luftfahrt, said they then used the Fischer-Tropsch process, first used by the Nazis, to turn the syngas into methanol.
Sasol has since perfected the 1925 German technology to turn coal into South Africa’s cleanest diesel and petrol, while Shell uses it to make jet fuel for aeroplanes.

Counting the cost

Solar Jet now has to count the cost of implementing the technology on an industrial scale.
When Sasol expanded globally after 1994 and fuel was still at $60 (R631,17) a vat of Brent crude, its refineries cost a lot more than a “normal” oil refinery, but once in place, Sasol could (and can) make oil quite a bit cheaper than $60 per vat.
Currently, with oil artificially maintained at over $100 (R1 051,95) per vat, according to oil pundit Leonardo Maugeri, Sasol is making a lot more money from us fuel addicts than what any right-thinking people, and even members of the SA Communist Party, deem fair.
Which is why we have to yell encouragement to the white coats at Solar Jet. They have, to date, made only one glass of jet fuel in a lab using simulated sunlight to prove the concept, and said it will take until next year to determine if the technology can scale up and remain both cost and energy-efficient.

‘Double toil, no trouble’

If Solar Jet does manage to make jet fuel from CO², H²O and lots of Vitamin D, they will have, in Sizmann’s words: “Truly sustainable fuels with virtually unlimited feedstocks”.
The ramifications are enormous for all humankind. As Professor Aldo Steinfeld, who led the fundamental research and development of the solar reactor at ETH Zürich, said in the paper Fuel from Sunlight, such a clean, universal sustainable energy source would avoid a major worldwide energy crisis.
Borrowing from Macbeth’s “Double, double toil and trouble, fire burn and cauldron bubble”, Steinfeld wrote that solar-based fuel research, such as he led at ETH Zürich, hopes “to avoid the bubbling cauldrons by riding out the 21st century on a sunbeam”.